Upper-rim functionalised calix[4]arenes for chemoselective Au3+ detection

Sean P. Bew; Sunil V. Sharma; William H. Gardiner

doi:10.1039/D3QO00021D

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Upper-rim functionalised calix[4]arenes for chemoselective Au³⁺ detection†

Sean P. Bew,

*^a Sunil V. Sharma

^b and William H. Gardiner^c

Author affiliations

* Corresponding authors

^a School of Chemistry, UEA, Norwich Research Park, Norwich, UK
E-mail: s.bew@uea.ac.uk

^b School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, Scotland, UK

^c Evotec UK Ltd, Innovation Drive, Milton Park, Abingdon, Oxfordshire, UK

Abstract

A unique, readily synthesised, upper-rim 1,3-difunctionalised calix[4]arene is reported; equipped with a fluorophore and an alkyne it mediates the efficient chemoselective detection of Au³⁺. Its ability to detect Au³⁺ is not perturbed by Au⁺ or excess competing and or contaminating metal e.g. platinum, cadmium, mercury, silver, sodium, magnesium or potassium cations.

This article is part of the themed collection: In memory of John S. Fossey – CAtalysis and SEnsing (CASE)

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Article information

DOI: https://doi.org/10.1039/D3QO00021D
Article type: Research Article
Submitted: 10 Janv. 2023
Accepted: 12 Marts 2023
First published: 14 Marts 2023
This article is Open Access

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Org. Chem. Front., 2023,10, 2397-2404

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Upper-rim functionalised calix[4]arenes for chemoselective Au³⁺ detection

S. P. Bew, S. V. Sharma and W. H. Gardiner, Org. Chem. Front., 2023, 10, 2397 DOI: 10.1039/D3QO00021D

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