Dielectric barrier discharge plasma catalysis as an alternative approach for the synthesis of ammonia: a review

Abstract

Numerous researchers have attempted to provide mild reactions and environmentally-friendly methods for NH₃ synthesis. Research on non-thermal plasma-assisted ammonia synthesis, notably the atmospheric-pressure nonthermal plasma synthesis of ammonia over catalysts, has recently gained attention in the academic literature. Since non-thermal plasma technology circumvents the existing crises and harsh conditions of the Haber–Bosch process, it can be considered as a promising alternative for clean synthesis of ammonia. Non-thermal dielectric barrier discharge (DBD) plasma has been extensively employed in the synthesis of ammonia due to its particular advantages such as the simple construction of DBD reactors, atmospheric operation at ambient temperature, and low cost. The combination of this plasma and catalytic materials can remarkably affect ammonia formation, energy efficiency, and the generation of by-products. The present article reviews plasma-catalysis ammonia synthesis in a dielectric barrier discharge reactor and the parameters affecting this synthesis system. The proposed mechanisms of ammonia production by this plasma catalysis system are discussed as well.