A p-type semi-conducting copper(I)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Chloé Andrade; Saly Hawila; Ahmad Abdallah; Jean-Luc Rukemampunzi; Adel Mesbah; Nathalie Guillou; Florent Perret; Stefan Wuttke; Thomas Niehaus; Régis Debord; Olivier Boisron; Stéphane Pailhès; Aude Demessence

doi:10.1039/D3TC02379F

A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient†

Chloé Andrade,^a Saly Hawila,^a Ahmad Abdallah,^a Jean-Luc Rukemampunzi,^a Adel Mesbah,

^a Nathalie Guillou,^b Florent Perret,^c Stefan Wuttke,

^de Thomas Niehaus,

^f Régis Debord,^f Olivier Boisron,^f Stéphane Pailhès

*^f and Aude Demessence

*^a

Author affiliations

* Corresponding authors

^a Univ Lyon, Université Claude Bernard Lyon 1, CNRS, Institut de Recherches sur la Catalyse et l’Environnement de Lyon (IRCELYON), UMR CNRS 5256, Villeurbanne, France
E-mail: aude.demessence@ircelyon.univ-lyon1.fr

^b Université Paris-Saclay, UVSQ, CNRS, Institut Lavoisier de Versailles (ILV), UMR 8180, Versailles, France

^c Univ Lyon, Université Claude Bernard Lyon 1, CNRS-INSA Lyon-CPE Lyon, Institut de Chimie et de Biochimie Moléculaires et Supramoléculaires (ICBMS), UMR 5246, Villeurbanne, France

^d BCMaterials (Basque Center for Materials, Applications & Nanostructures), University of the Basque Country (UPV/EHU), Leioa, Spain

^e Ikerbasque, Basque Foundation for Science, Bilbao, Spain

^f Univ Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Lumière Matière (ILM), UMR 5306, Villeurbanne, France

Abstract

A new p-type semi-conducting and 2D coordination polymer (CP) based on a thiolate ligand and Cu(+I) exhibits a record Seebeck coefficient among CPs, equivalent to that obtained for inorganic compounds. Such a high value originates from the 1D {Cu–S}_n tubular inorganic network, which is connected through the bridging 1,3-benzenedithiolate ligand.

This article is part of the themed collection: Fundamentals and Applications of Functional Framework Materials

Journal of Materials Chemistry C

A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient†

Abstract

Supplementary files

Article information

Download Citation

Permissions

A p-type semi-conducting copper(I)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Social activity

Search articles by author

Spotlight

Advertisements