Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

Siad Wolff; Annabelle Ponsonby; André Dallmann; Christian Herwig; Fabian Beckmann; Beatrice Cula; Christian Limberg

doi:10.1039/D4CC01682C

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Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes†

Siad Wolff,

^a Annabelle Ponsonby,^a André Dallmann,

^a Christian Herwig,^a Fabian Beckmann,^a Beatrice Cula^a and Christian Limberg

*^a

Author affiliations

* Corresponding authors

^a Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin, Germany
E-mail: Christian.limberg@chemie.hu-berlin.de

Abstract

Nickel carbonite complexes supported by alkaline earth metals have been accessed via salt-metathesis of the corresponding alkali metal precursors. The new complexes undergo Schlenk-like exchange reactions in solution which have been investigated by NMR spectroscopy. Also their reactivity towards epoxides and carbon monoxide was studied.

This article is part of the themed collection: Small Molecule Transformations of Energy Relevance

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DOI: https://doi.org/10.1039/D4CC01682C
Article type: Communication
Submitted: 10 Apr. 2024
Accepted: 07 Maijs 2024
First published: 07 Maijs 2024
This article is Open Access

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Chem. Commun., 2024,60, 5816-5819

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Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

S. Wolff, A. Ponsonby, A. Dallmann, C. Herwig, F. Beckmann, B. Cula and C. Limberg, Chem. Commun., 2024, 60, 5816 DOI: 10.1039/D4CC01682C

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Chemical Communications

Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes†

Abstract

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Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

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