Issue 65, 2024
From the journal:

Chemical Communications

A neutral crystalline imino-substituted silyl radical†

Fiona J. Kiefer,a   Arseni Kostenko, ORCID logo a   Richard Holzner ORCID logo a  and  Shigeyoshi Inoue ORCID logo *a  

* Corresponding authors

a TUM School of Natural Sciences, Department of Chemistry, Wacker-Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, 85748 Garching bei München, Germany
E-mail: s.inoue@tum.de

Abstract

The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

Graphical abstract: A neutral crystalline imino-substituted silyl radical

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Article information

DOI
https://doi.org/10.1039/D4CC02167C
Article type
Communication
Submitted
04 Maijs 2024
Accepted
09 Jūl. 2024
First published
10 Jūl. 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 8577-8580

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A neutral crystalline imino-substituted silyl radical

F. J. Kiefer, A. Kostenko, R. Holzner and S. Inoue, Chem. Commun., 2024, 60, 8577 DOI: 10.1039/D4CC02167C

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