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Chemical Communications

Double dehydrogenative coupling of amino alcohols with primary alcohols under Mn(i) catalysis†

Ganesan Sivakumar, ORCID logo a   Abhijith Karattil Suresh,a   Smruti Rekha Padhya  and  Ekambaram Balaraman ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati – 517507, Andhra Pradesh, India
E-mail: eb.raman@iisertirupati.ac.in

Abstract

Herein, we unveil a method for synthesizing substituted pyrrole and pyrazine compounds via a double dehydrogenative coupling of amino alcohols with primary alcohols, facilitated by Mn(I)–PNP catalysis, which uniquely enables the simultaneous formation of C–C and C–N bonds.

Graphical abstract: Double dehydrogenative coupling of amino alcohols with primary alcohols under Mn(i) catalysis

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DOI
https://doi.org/10.1039/D4CC03595J
Article type
Communication
Submitted
19 Jūl. 2024
Accepted
22 Okt. 2024
First published
23 Okt. 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024, Advance Article

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Double dehydrogenative coupling of amino alcohols with primary alcohols under Mn(I) catalysis

G. Sivakumar, A. K. Suresh, S. R. Padhy and E. Balaraman, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC03595J

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