Issue 81, 2024
From the journal:

Chemical Communications

Ligand effects on gas adsorption in nanoporous phthalocyanine crystals†

Nikolaos-Angelos Stamos,a   Charles J. McMonagle,b   Gemma F. Turner,d   David R. Allan, ORCID logo c   Mark R. Warren,c   Anna J. Warren, ORCID logo c   Neil B. McKeown ORCID logo *a  and  Stephen A. Moggach ORCID logo *d  

* Corresponding authors

a EastChem School of Chemistry, David Brewster Road, The University of Edinburgh, Edinburgh, UK

b Swiss–Norwegian Beamlines, European Synchrotron Radiation Facility, Grenoble 38043, France

c Diamond House, Harwell Science and Innovation Campus, Fermi Ave, Didcot OX11 0DE, UK

d School of Molecular Sciences, The University of Western Australia, 35 Stirling Highway, Crawley, Perth, WA 6009, Australia
E-mail: stephen.moggach@uwa.edu.au

Abstract

X-ray diffraction is used to study the sorption of CO and NO in two phthalocyanine nanoporous crystals (PNCs) with 4,4′ bipyridine or 4,4′ bipyrimidine trans coordinated to open Co2+ sites, demonstrating how the trans coordinated ligands influence the gas sorption properties and structures of the PNCs.

Graphical abstract: Ligand effects on gas adsorption in nanoporous phthalocyanine crystals

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Article information

DOI
https://doi.org/10.1039/D4CC03896G
Article type
Communication
Submitted
01 Aug. 2024
Accepted
18 Sept. 2024
First published
20 Sept. 2024

Chem. Commun., 2024,60, 11508-11511

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Ligand effects on gas adsorption in nanoporous phthalocyanine crystals

N. Stamos, C. J. McMonagle, G. F. Turner, D. R. Allan, M. R. Warren, A. J. Warren, N. B. McKeown and S. A. Moggach, Chem. Commun., 2024, 60, 11508 DOI: 10.1039/D4CC03896G

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