Transport-driven chemical oscillations: a review

Abstract

Chemical oscillators attract transversal interest not only as useful models for understanding and controlling (bio)chemical complexity far from the equilibrium, but also as a promising means to design smart materials and power synthetic functional behaviors. We review and classify oscillatory phenomena in systems where a periodic variation in the concentration of the constitutive chemical species is induced by transport instabilities either triggered by simple reactions or without any reactive process at play. These phenomena, where the origin of the dynamical complexity is shifted from chemical to physical nonlinearities, can facilitate a variety of processes commonly encountered in chemistry and chemical engineering. We present an excursus through the main examples, discussing phenomenology, properties and modeling of different mechanisms that can lead to these kinds of oscillations. In particular, we reproduce the relevant results reported in the pertinent literature and, in parallel, propose new kinds of proof-of-concept systems substantiated by preliminary studies which can inspire new research lines. In the landscape of physically driven chemical oscillations, we devote particular attention to transport phenomena, actively or passively combined to (reactive or nonreactive) chemical species, which provide multiple pathways towards spontaneous oscillatory instabilities. Though with different specificities, the great part of these systems can be reduced to a common theoretical description. We finally overview possible perspectives in the study of physically driven oscillatory instabilities, showing how the related control can impact fundamental and applied open problems, ranging from origin of life studies to the optimization of processes with environmental relevance.