Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Pascal Jurt; Juan José Gamboa-Carballo; Clara Schweinzer; Daniel Himmelbauer; Debora Thöny; Thomas L. Gianetti; Monica Trincado; Hansjörg Grützmacher

doi:10.1039/D4DT01520G

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Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes†

Pascal Jurt,^a Juan José Gamboa-Carballo,

^ab Clara Schweinzer,

^a Daniel Himmelbauer,

^c Debora Thöny,

^a Thomas L. Gianetti,*^d Monica Trincado

*^ae and Hansjörg Grützmacher

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland
E-mail: hgruetzmacher@ethz.ch

^b Higher Institute of Technologies and Applied Sciences (InSTEC), University of Havana, Ave. S. Allende 1110, 10600 Havana, Cuba

^c Institute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163, A-1060 Vienna, Austria

^d Department of Chemistry and Biochemistry, University of Arizona, University Blvd., Tucson, AZ 85719, USA
E-mail: tgianetti@email.arizona.edu

^e Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland
E-mail: monica.trincado@chem.uzh.ch

Abstract

This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

This article is part of the themed collection: Dalton Transactions HOT Articles

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Article information

DOI: https://doi.org/10.1039/D4DT01520G
Article type: Paper
Submitted: 24 Maijs 2024
Accepted: 24 Jūl. 2024
First published: 13 Aug. 2024
This article is Open Access

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Dalton Trans., 2024,53, 14212-14218

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Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

P. Jurt, J. J. Gamboa-Carballo, C. Schweinzer, D. Himmelbauer, D. Thöny, T. L. Gianetti, M. Trincado and H. Grützmacher, Dalton Trans., 2024, 53, 14212 DOI: 10.1039/D4DT01520G

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Dalton Transactions

Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes†

Abstract

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Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

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