Characterizing catalyst function and transformations in the plasma reduction of CO2 on atomic layer deposition-synthesized catalysts

Abstract

The enhancement of CO₂ reduction in atmospheric-pressure, non-thermal plasma has been shown using a variety of catalyst systems with ranging composition, particle sizes, and morphologies. Improvements in CO₂ conversion can be attained by choice of catalyst material. However, inhomogeneity in the material distribution arising from the synthesis affects the catalytically active surface area and dielectric environment that modulates the plasma properties near the catalyst. Atomic layer deposition (ALD) can be used to control the composition of ultra-thin layers on support materials. We used ALD to synthesize metal oxide catalyst coatings on high surface area supports. We found that TiO₂ achieved significantly higher yields of CO₂ conversion (to CO and O₂) at low reactor power compared to ZnO or Al₂O₃, materials commonly used as a support for other catalysts. We also observed an unexpected increase in the catalytic activity on ZnO with increasing power. The results here suggest that ALD can unambiguously isolate the catalytic effects of materials in plasma reactors.