Issue 21, 2014
From the journal:

Chemical Communications

Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex†

Alexander F. R. Kilpatricka  and  F. Geoffrey N. Cloke*a  

* Corresponding authors

a Department of Chemistry, School of Life Sciences, University of Sussex, Brighton, UK
E-mail: f.g.cloke@sussex.ac.uk
Fax: +44 (0)1273 876 687

Abstract

The bimetallic bis(pentalene) complex (μ:η5,η5-Pn†)2Ti2 reductively splits CO2 to form a bis(oxo) bridged dimer [(η8-Pn†)Ti(μ-O)]2, in which the Ti–Ti bond has been cleaved, and the dicarbonyl complex (μ:η5,η5-Pn†)2[Ti(CO)]2.

Graphical abstract: Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

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Article information

DOI
https://doi.org/10.1039/C3CC48379G
Article type
Communication
Submitted
01 Nov. 2013
Accepted
17 Janv. 2014
First published
17 Janv. 2014

Chem. Commun., 2014,50, 2769-2771

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Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

A. F. R. Kilpatrick and F. G. N. Cloke, Chem. Commun., 2014, 50, 2769 DOI: 10.1039/C3CC48379G

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