Reversible and efficient SO2 capture by a chemically stable MOF CAU-10: experiments and simulations

J. Antonio Zárate; Eduardo Domínguez-Ojeda; Elí Sánchez-González; Eva Martínez-Ahumada; Valeria B. López-Cervantes; Daryl R. Williams; Vladimir Martis; Ilich A. Ibarra; José Alejandre

doi:10.1039/D0DT01595D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Reversible and efficient SO₂ capture by a chemically stable MOF CAU-10: experiments and simulations†

J. Antonio Zárate,

‡^a Eduardo Domínguez-Ojeda,

‡^b Elí Sánchez-González,

^c Eva Martínez-Ahumada,^a Valeria B. López-Cervantes,^a Daryl R. Williams,^d Vladimir Martis,^e Ilich A. Ibarra

*^a and José Alejandre*^b

Author affiliations

* Corresponding authors

^a Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Coyoacán, Ciudad de México, Mexico
E-mail: argel@unam.mx
Fax: +52 55 5622 4595

^b Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, San Rafael Atlixco 186, Col. Vicentina, Iztapalapa, C. P. 09340 Ciudad de México, Mexico
E-mail: jra@xanum.uam.mx

^c Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

^d Surfaces and Particle Engineering Laboratory (SPEL), Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, UK

^e Surface Measurement Systems, Unit 5, Wharfside, Rosemont Road, London HA0 4PE, UK

Abstract

The adsorption of sulphur dioxide (SO₂) in CAU-10 is obtained with the use of advanced experimental and computational tools to gain insight into the molecular mechanisms responsible for the adsorption of SO₂. It is shown that the adsorption by CAU-10 is highly energy efficient and that van der Waals interactions are the driving force that controls adsorption in this system.

This article is part of the themed collection: Celebrating Latin American Talent in Chemistry

Download options Please wait...

Supplementary files

Supplementary information PDF (778K)

Article information

DOI: https://doi.org/10.1039/D0DT01595D
Article type: Communication
Submitted: 01 Maijs 2020
Accepted: 21 Jūn. 2020
First published: 22 Jūn. 2020

Download Citation

Dalton Trans., 2020,49, 9203-9207

Permissions

Request permissions

Reversible and efficient SO₂ capture by a chemically stable MOF CAU-10: experiments and simulations

J. A. Zárate, E. Domínguez-Ojeda, E. Sánchez-González, E. Martínez-Ahumada, V. B. López-Cervantes, D. R. Williams, V. Martis, I. A. Ibarra and J. Alejandre, Dalton Trans., 2020, 49, 9203 DOI: 10.1039/D0DT01595D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions