Issue 57, 2021
From the journal:

Chemical Communications

Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds†

Peng-Fei Li,ab   Chun-Li Hu,a   Ya-Ping Gong,a   Fang Kong ORCID logo *ac  and  Jiang-Gao Mao ORCID logo a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
E-mail: kongfang@fjirsm.ac.cn

b College of Chemical Engineering, Fuzhou University, Fuzhou 350116, P. R. China

c University of Chinese Academy of Sciences, Beijing 100190, P. R. China

Abstract

Our exploration of novel inorganic solids with large birefringence in the d10 Metal–Te4+–SO42− system afforded four new sulfate tellurites, Ga2(TeO3)(SO4)(OH)2, In2(TeO3)2(SO4)(H2O), Zn4(Te3O7)2(SO4)2(H2O) and Hg3(Te3O8)(SO4). Notably, Hg3(Te3O8)(SO4) exhibits the largest birefringence at 532 nm (0.184) and 1064 nm (0.166) among the reported metal sulfate tellurites.

Graphical abstract: Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1CC02494A
Article type
Communication
Submitted
11 Maijs 2021
Accepted
15 Jūn. 2021
First published
16 Jūn. 2021

Chem. Commun., 2021,57, 7039-7042

Permissions

Request permissions

Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds

P. Li, C. Hu, Y. Gong, F. Kong and J. Mao, Chem. Commun., 2021, 57, 7039 DOI: 10.1039/D1CC02494A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements