Efficient detection of p-nitrophenol via a polypyrrole flower-decorated nickel foam-based electrochemical sensor

Abstract

p-Nitrophenol (p-NP) is known as a common contaminant found in wastewater, agricultural runoff, and industrial effluents which can degrade water quality and cause potential carcinogenic and toxic effects on the human body. Its detection is essential for public health, industrial safety, environmental protection, and regulatory compliance, underscoring its broad applicability. In this study, a novel electrochemical sensor based on polypyrrole (PPy) flowers assembled via nanotubes was developed for the sensitive determination of p-NP. The nickel (Ni) foam modified with PPy flowers functioned as the working electrode and showed selectivity toward p-NP in a phosphate buffer medium at pH 7.0. Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) techniques were utilized for the sensitive determination of p-NP. Under the optimum conditions, the peak currents of DPV versus the concentrations of p-NP in the range of 0.01–20 nM showed a good linear relationship (R² = 0.9943), and the limit of detection (LOD) was calculated to be 7.18 pM (signal-to-noise ratio of 3, S/N = 3). The fabricated electrochemical p-NP sensor exhibited high sensitivity, a low detection limit, and a low response time. The recoveries of p-NP in real samples of groundwater and tap water using the PPy Fls/Ni foam electrode were in the range of 91.0–108.4% with a relative standard deviation (RSD) in the range of 6.65%. Consequently, the PPy Fls/Ni foam electrode could be applied as a rapid, precise, and sensitive electrochemical sensor platform for aqueous p-NP quantification and determination.