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We have developed a simple soft template-mediated coupling construction approach to achieve an unexplored sandwiched mesoporous polypyrrole nanocoating/single-crystal Ag nanoplate hybrid by a one-step inorganic/organic redox reaction at the liquid interface, and the hybrid possesses an adjustable meso-structure and architecture, strong near-infrared absorption and Raman enhancement effect, and outstanding chemical sensing performance.

Graphical abstract: Soft template-mediated coupling construction of sandwiched mesoporous PPy/Ag nanoplates for rapid and selective NH3 sensing

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