Two rare indium-based porous metal–metalloporphyrin frameworks exhibiting interesting CO2 uptake

Wen-Yang Gao; Zhuxiu Zhang; Lindsay Cash; Lukasz Wojtas; Yu-Sheng Chen; Shengqian Ma

doi:10.1039/C3CE41090K

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Two rare indium-based porous metal–metalloporphyrin frameworks exhibiting interesting CO₂ uptake†

Wen-Yang Gao,‡^a Zhuxiu Zhang,‡^a Lindsay Cash,^a Lukasz Wojtas,^a Yu-Sheng Chen^b and Shengqian Ma*^a

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* Corresponding authors

^a Department of Chemistry, University of South Florida, 4202 East Flower Avenue, Tampa, Florida 33620, United States
E-mail: sqma@usf.edu
Fax: +1-813-974 3203
Tel: +1-813-974 5217

^b ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago, 9700 S. Cass Avenue, Argonne, IL 60439, USA

Abstract

Two rare indium-based porous metal–metalloporphyrin frameworks (MMPFs), MMPF-7 and MMPF-8, were constructed by self-assembly of In(III) and two custom-designed porphyrin–tetracarboxylate ligands. MMPF-7 and MMPF-8 possess the pts topology and exhibit interesting CO₂ adsorption properties.

This article is part of the themed collection: Structural Design of Coordination Polymers

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Article information

DOI: https://doi.org/10.1039/C3CE41090K
Article type: Communication
Submitted: 10 jun 2013
Accepted: 10 jul 2013
First published: 11 jul 2013

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CrystEngComm, 2013,15, 9320-9323

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Two rare indium-based porous metal–metalloporphyrin frameworks exhibiting interesting CO₂ uptake

W. Gao, Z. Zhang, L. Cash, L. Wojtas, Y. Chen and S. Ma, CrystEngComm, 2013, 15, 9320 DOI: 10.1039/C3CE41090K

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