Issue 45, 2013

A highly porous agw-type metal–organic framework and its CO2 and H2adsorption capacity

Abstract

An unsymmetrical tricarboxylate ligand with linking alkyne moiety has been used to construct a highly porous metal–organic framework with agw topology. The obtained Cu(II) MOF exhibits a high BET surface area of 3337.0 m2 g−1, a large capacity of CO2 (21.2 mmol g−1 at 298 K and 20 bar) and a good H2 adsorption (5.8 wt% at 77 K and 20 bar).

Graphical abstract: A highly porous agw-type metal–organic framework and its CO2 and H2 adsorption capacity

Supplementary files

Article information

Article type
Communication
Submitted
12 jun 2013
Accepted
14 aug 2013
First published
15 aug 2013

CrystEngComm, 2013,15, 9348-9351

A highly porous agw-type metal–organic framework and its CO2 and H2 adsorption capacity

Z. Lu, L. Du, B. Zheng, J. Bai, M. Zhang and R. Yun, CrystEngComm, 2013, 15, 9348 DOI: 10.1039/C3CE41119B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements