Double uranium oxo cations derived from uranyl by borane or silane reduction

Abstract

A new type of double uranium oxo cation [O–U–O–U–O]⁴⁺ is prepared by selective oxygen-atom abstraction from macrocyclic uranyl complexes using either boranes or silanes. A significant degree of multiple UO bonding is evident throughout the U₂O₃ core, but either trans-,cis- or trans-,trans-OUOUO motifs can be isolated as boron- or silicon-capped oxo complexes. Further controlled deoxygenation of the borylated system is also possible.