Unbalanced MOF-on-MOF growth for the production of a lopsided core–shell of MIL-88B@MIL-88A with mismatched cell parameters

Dooyoung Kim; Gihyun Lee; Sojin Oh; Moonhyun Oh

doi:10.1039/C8CC08456D

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Unbalanced MOF-on-MOF growth for the production of a lopsided core–shell of MIL-88B@MIL-88A with mismatched cell parameters†

Dooyoung Kim,^a Gihyun Lee,^a Sojin Oh^a and Moonhyun Oh

*^a

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* Corresponding authors

^a Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749, Korea
E-mail: moh@yonsei.ac.kr
Fax: +82 2 364 7050
Tel: +82 2 2123 5637

Abstract

The unbalanced MOF-on-MOF growth of MIL-88A on the MIL-88B template, where both MOFs have a similar three-dimensional hexagonal structure but with mismatched cell parameters, results in the formation of an atypical lopsided core–shell of MIL-88B@MIL-88A with an off-centered core. The formation mechanism of the lopsided core–shell of MIL-88B@MIL-88A is verified via monitoring the growth process.

This article is part of the themed collection: Celebrating the 75th Anniversary of the Korean Chemical Society (KCS)

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Article information

DOI: https://doi.org/10.1039/C8CC08456D
Article type: Communication
Submitted: 23 okt 2018
Accepted: 22 nov 2018
First published: 22 nov 2018

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Chem. Commun., 2019,55, 43-46

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Unbalanced MOF-on-MOF growth for the production of a lopsided core–shell of MIL-88B@MIL-88A with mismatched cell parameters

D. Kim, G. Lee, S. Oh and M. Oh, Chem. Commun., 2019, 55, 43 DOI: 10.1039/C8CC08456D

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Chemical Communications

Unbalanced MOF-on-MOF growth for the production of a lopsided core–shell of MIL-88B@MIL-88A with mismatched cell parameters†

Abstract

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Unbalanced MOF-on-MOF growth for the production of a lopsided core–shell of MIL-88B@MIL-88A with mismatched cell parameters

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