Organic template-assisted green synthesis of CoMoO4 nanomaterials for the investigation of energy storage properties

Abstract

Transitional metal oxide nanomaterials are considered to be potential electrode materials for supercapacitors. Therefore, in the past few decades, huge efforts have been devoted towards the sustainable synthesis of metal oxide nanomaterials. Herein, we report a synergistic approach to synthesize spherical-shaped CoMoO₄ electrode materials using an inorganic–organic template via the hydrothermal route. As per the synthesis strategy, the precursor solution was reacted with the organic compounds of E. cognata to tailor the surface chemistry and morphology of CoMoO₄ by organic species. The modified CoMoO₄ nanomaterials revealed a particle size of 23 nm by X-ray diffraction. Furthermore, the synthesized material was scrutinized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, field emission scanning electron microscopy and energy dispersive spectroscopy. The optical band gap energy of 3.6 eV was calculated by a Tauc plot. Gas chromatography-mass spectrometry identified cyclobutanol (C₄H₈O) and octodrine (C₈H₁₉N) as the major stabilizing agents of the CoMoO₄ nanomaterial. Finally, it was revealed that the bioorganic framework-derived CoMoO₄ electrode exhibited a capacitance of 294 F g⁻¹ by cyclic voltammetry with a maximum energy density of 7.3 W h kg⁻¹ and power density of 7227.525 W kg⁻¹. Consequently, the nanofeatures and organic compounds of E. cognata were found to enhance the electrochemical behaviour of the CoMoO₄-fabricated electrode towards supercapacitor applications.