Group 14 metallole dianions as η5-coordinating ligands

Abstract

As heavier aromatic analogs of the cyclopentadienides, group 14 dianionic metalloles exhibit more versatile reactivity and coordination modes due to the additional lone pair at the heteroatom. Compared to the well-established chemistry of monoanionic cyclopentadienide ligands, the coordination chemistry with those dianionic ligands remains underexplored. This perspective provides an overview of literature-known examples of group 14 metallole dianions (silole, germole, stannole and plumbole) adopting η⁵-coordinating modes. The diverse coordination modes and reactivity exhibited by these compounds highlight their potential as intriguing ligands in organometallic chemistry.