Issue 82, 2024
From the journal:

Chemical Communications

Exploring aromatic rings with planar tetracoordinate group 13–15 atoms†

Dumer S. Sacanamboy, ORCID logo ab   Pamela L. Gamero-Begazo, ORCID logo b   Kevin E. Parco-Valencia, ORCID logo b   Diego Inostroza, ORCID logo c   Lina Ruiz, ORCID logo d   Luis Leyva-Parra, ORCID logo *e   Gabriel Merino ORCID logo *f  and  William Tiznado ORCID logo *a  

* Corresponding authors

a Universidad Andres Bello, Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Centro de Química Teórica & Computacional (CQT&C), Avenida República 275, 8370146 Santiago de Chile, Chile
E-mail: wtiznado@unab.cl

b Doctorado en Fisicoquímica Molecular, Facultad de Ciencias Exactas, Universidad Andres Bello, Avenida República 275, Santiago de Chile, Chile

c Laboratoire de Chimie Théorique, LCT, Sorbonne Université, CNRS, F-75005 Paris, France

d Instituto de Ciencias Biomédicas, Facultad de Ciencias de la Salud, Universidad Autónoma de Chile, Santiago de Chile, Chile

e Facultad de Ingeniería y Arquitectura, Universidad Central de Chile (UCEN), Santa Isabel 1186, Santiago, Chile
E-mail: luis.leyva@ucentral.cl

f Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados Mérida Km. 6 Antigua carretera a Progreso Apdo. Postal 73, Cordemex, Yuc., Mérida, Mexico
E-mail: gmerino@cinvestav.mx

Abstract

This study examines systems containing planar tetracoordinate group 13–15 atoms (E) within pentagonal C4H2E rings bridged by Si or Ge atoms. A detailed chemical bonding analysis of eleven candidates shows that true tetracoordination is achieved only in the C4H2NGe2+ system.

Graphical abstract: Exploring aromatic rings with planar tetracoordinate group 13–15 atoms

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Article information

DOI
https://doi.org/10.1039/D4CC02780A
Article type
Communication
Submitted
08 jun 2024
Accepted
18 sep 2024
First published
18 sep 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 11790-11793

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Exploring aromatic rings with planar tetracoordinate group 13–15 atoms

D. S. Sacanamboy, P. L. Gamero-Begazo, K. E. Parco-Valencia, D. Inostroza, L. Ruiz, L. Leyva-Parra, G. Merino and W. Tiznado, Chem. Commun., 2024, 60, 11790 DOI: 10.1039/D4CC02780A

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