A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

Daniel Podgornii; Jan van Leusen; Victor Ch. Kravtsov; Paul Kögerler; Svetlana G. Baca

doi:10.1039/D1CE00777G

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A {Na₂Fe₁₀} isobutyrate cluster, interlinked into 1D chains†

Daniel Podgornii,^a Jan van Leusen,

^b Victor Ch. Kravtsov,

^a Paul Kögerler

*^b and Svetlana G. Baca

*^a

Author affiliations

* Corresponding authors

^a Institute of Applied Physics, Academiei 5, 2028 Chisinau, Republic of Moldova
E-mail: sbaca_md@yahoo.com

^b Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de

Abstract

Charge-neutral [Na₂Fe₁₀O₆(OH)₄(isobutyrate)₁₄(MeO)₂(MeCN)₂] coordination clusters, comprising a hollow ‘Chinese lantern’-like shell of six condensed planar triangular {Fe^III₃(μ₃-O)} motifs, form upon ultrasonication of trinuclear Fe(III) isobutyrate units in acetonitrile in the presence of sodium azide and 4,4′-bipyridine (bpy), resulting in {[Na₂Fe₁₀O₆(OH)₄(isobutyrate)₁₄(bpy)(MeO)₂(MeCN)₂]·MeOH}_n in which the dodecanuclear cluster units are bpy-bridged into 1D chains.

This article is part of the themed collection: Coordination Networks

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Article information

DOI: https://doi.org/10.1039/D1CE00777G
Article type: Communication
Submitted: 10 jun 2021
Accepted: 19 jul 2021
First published: 20 jul 2021

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CrystEngComm, 2021,23, 5153-5156

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A {Na₂Fe₁₀} isobutyrate cluster, interlinked into 1D chains

D. Podgornii, J. van Leusen, V. Ch. Kravtsov, P. Kögerler and S. G. Baca, CrystEngComm, 2021, 23, 5153 DOI: 10.1039/D1CE00777G

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