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Abstract | Cited by

Rh(0)/Rh(III) core–shell nanoparticles were prepared by surface oxidation of Rh nanoparticles with N-bromosuccinimide. They were employed as heterogeneous catalysts for cyclic carbonate synthesis from propylene oxide and CO2, and exhibited high activity and excellent recyclability due to Lewis acidic Rh(III) species on the shells.

Graphical abstract: Rh(0)/Rh(iii) core–shell nanoparticles as heterogeneous catalysts for cyclic carbonate synthesis

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