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Abstract | Cited by

Gold(II) species catalyse the cyclisation of N(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the saturated gold(I) complex is inactive. Redox-switching between gold(II) and gold(I) turns catalytic turnover on and off.

Graphical abstract: Gold(ii) in redox-switchable gold(i) catalysis

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