Benzoic acid hydrogenation faces a persistent activity-selectivity trade-off. Ru/HfB2 overcomes this challenge via strong metal-support interactions that generate electron-rich Ruδ- sites, enabling >99% conversion and selectivity under mild conditions.
X. Chen, C. Zhou, G. Zhou, S. Wang, S. Zhang, T. Song, R. Li, H. Cai, B. Wang, Y. Yue and J. Zhao, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC03876F
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