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Abstract | Cited by

A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.

Graphical abstract: A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework

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