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A cost-effective N/S co-doped carbon cloth has been synthesized by pyrolysis of waste facial masks as robust free-standing electrodes with high capacitance for assembling anti-freezing flexible quasi-solid-state supercapacitors with high energy and good adaptability at low temperatures of −20 °C.

Graphical abstract: A N/S co-doped free-standing carbon electrode derived from waste facial masks for anti-freezing flexible quasi-solid-state supercapacitors

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