Issue 53, 2017

Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts

Abstract

We report a novel method for the preparation of PBP-pincer complexes from bis(phosphine)boronium salts. The central (R3P)2HB-moiety in a palladium complex is demonstrated to be a L-type ligand, therewith completing a series of pincer-type complexes with Z-, X- and L-type boron-based ligands, respectively.

Graphical abstract: Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts

Supplementary files

Article information

Article type
Communication
Submitted
27 Mac 2017
Accepted
27 Apr 2017
First published
27 Apr 2017

Chem. Commun., 2017,53, 7230-7233

Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts

M. Grätz, A. Bäcker, L. Vondung, L. Maser, A. Reincke and R. Langer, Chem. Commun., 2017, 53, 7230 DOI: 10.1039/C7CC02335A

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