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Incorporating bipyridine units into the matrix of conjugated microporous polymers (CMPs) boosts exciton dissociation, charge separation, and oxidation capacity. Consequently, the bipyridine-modified CMPs exhibit an impressive U(VI) separation rate (404 μmol g−1 h−1) under sacrificial agent-free conditions, outperforming the results of its counterparts without bipyridine units and other documented CMPs.

Graphical abstract: Bipyridine-based conjugated microporous polymers for boosted photocatalytic U(vi) separation

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