Murugan Subaramanian, Ganesan Sivakumar and Ekambaram Balaraman
Org. Biomol. Chem., 2021,19, 4213-4227
DOI:
10.1039/D1OB00080B,
Review Article
In recent times, earth-abundant 3d-transition-metal catalysts have attracted much attention in contemporary catalysis. They have been widely employed as suitable alternatives to their counterparts noble metals. In particular, nickel catalysts provide distinctive redox properties; thus, their efficiency in sustainable organic transformations is manifold. In this review article, recent advances in nickel-catalyzed hydrogen auto-transfer (HA) and acceptorless dehydrogenative coupling (ADC) reactions for the construction of C–C and C–N bonds have been discussed.