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The optical properties of [Zn2(NDC)2(DPNI)]0/−/2− (NDC = 2,7-naphthalene dicarboxylate, DPNI = N,N′-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide), a redox-active metal–organic framework, have been examined using a simple and robust in situ solid state UV-Vis-NIR spectroelectrochemical technique.

Graphical abstract: Rapid determination of the optical and redox properties of a metal–organic framework via in situ solid state spectroelectrochemistry

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