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Abstract | Cited by

Meta-GGA calculations of the ambient and high-pressure polymorphs of silver difluoride indicate that the compression-induced structural changes lead to a 3.5-fold increase in the strength of antiferromagnetic spin–spin interactions resulting in coupling constant values higher than those found for record-holding oxocuprates(II).

Graphical abstract: Dramatic enhancement of spin–spin coupling and quenching of magnetic dimensionality in compressed silver difluoride

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