Minji Lee, Hyunju Noh and Youngsuk Kim
Chem. Commun., 2024,60, 13867-13870
DOI:
10.1039/D4CC04582C,
Communication
Novel palladium and nickel–sulfur clusters were synthesized using a diamidocarbene-derived carbon disulfide ligand. Structural characterization revealed a tetranuclear metal–sulfur cluster geometry with each metal center exhibiting square-planar coordination. The ligand was redox-active, accommodating oxidation states ranging from 0 to −2.