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A series of ferrocene-grafted/loaded stable metal–organic frameworks (MOFs), based on the classical NH2-MIL-125(Ti), were prepared to improve the light absorption and photogenerated charge migration of photocatalysts, which can achieve enhanced CO2-to-HCOOH reduction performance. This work highlights the obvious advantage of the modifiability of the MOF structure in optimizing the performance of the photocatalytic CO2RR.

Graphical abstract: A ferrocene-modified stable metal–organic framework for efficient CO2 photoreduction reaction

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