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We show that the nuclearity of the 2-D coordination polymers of carboxylated pillar[5]arene with Sr(II) cations can be varied with the aid of 1,10-phenanthroline as a coligand. In the absence of metal cations, pillar[5]arene and 1,10-phenanthroline form an exclusion type supramolecular assembly through outer-surface interactions.

Graphical abstract: Incorporation of carboxylated pillar[5]arene and strontium(ii) into supramolecular coordination complexes of different nuclearities

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