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Abstract | Cited by

A homodinuclear Ni2-Schiff base1 complex (0.1–1 mol%) promoted the direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde, giving hydroxymethylated adducts in 94–66% ee.

Graphical abstract: Direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde promoted by a dinuclear Ni2-Schiff base complex

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