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Abstract | Cited by

N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe3)3 with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)3.31][AsCO] with imidazolium chlorides.

Graphical abstract: N-Heterocyclic carbene-stabilised arsinidene (AsH)

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