Issue 52, 2016

Selective precipitation of alkyl dihalides using a newly synthesized water-soluble bisphosphorylpillar[5]arene

Abstract

Bisphosphorylpillar[5]arenes (H1 and H2) were synthesized and used to study the host–guest complexation in organic solvents and water. The interactions between the guests and the phosphate of the hosts lead to strong binding towards alkyl dihalides and alkyldiammonium ions. H2 may be used to detect or separate alkyl dihalides in water due to the rapid precipitation of the complex.

Graphical abstract: Selective precipitation of alkyl dihalides using a newly synthesized water-soluble bisphosphorylpillar[5]arene

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
26 apr 2016
Accepted
12 may 2016
First published
12 may 2016

Chem. Commun., 2016,52, 8075-8078

Selective precipitation of alkyl dihalides using a newly synthesized water-soluble bisphosphorylpillar[5]arene

W. Cheng, H. Tang, R. Wang, L. Wang, H. Meier and D. Cao, Chem. Commun., 2016, 52, 8075 DOI: 10.1039/C6CC03494B

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