Issue 25, 2010

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex

Abstract

The synthesis and characterization of two-coordinate cobalt(II) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment.

Graphical abstract: Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex

Supplementary files

Article information

Article type
Communication
Submitted
22 yan 2010
Accepted
15 apr 2010
First published
20 may 2010

Chem. Commun., 2010,46, 4466-4468

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex

C. Ni, T. A. Stich, G. J. Long and P. P. Power, Chem. Commun., 2010, 46, 4466 DOI: 10.1039/C001483D

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