Issue 25, 2010
From the journal:

Chemical Communications

A scandium terminal imido complex: synthesis, structure and DFT studies†

Erli Lu,a   Yuxue Lia  and  Yaofeng Chen*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China
E-mail: yaofchen@mail.sioc.ac.cn
Fax: 0085-21-64166128

Abstract

The first rare earth metal terminal imido complex has been isolated and structurally characterized. The complex has an extremely short M–N bond length and a nearly linear M–N–C angle. DFT studies showed two p orbitals of Nimido atom form two bonds with two d orbitals of rare earth metal ion.

Graphical abstract: A scandium terminal imido complex: synthesis, structure and DFT studies

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Article information

DOI
https://doi.org/10.1039/C002870C
Article type
Communication
Submitted
10 Feb 2010
Accepted
13 Apr 2010
First published
12 May 2010

Chem. Commun., 2010,46, 4469-4471

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A scandium terminal imido complex: synthesis, structure and DFT studies

E. Lu, Y. Li and Y. Chen, Chem. Commun., 2010, 46, 4469 DOI: 10.1039/C002870C

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