Themed collection Journal of Materials Chemistry A Recent Review Articles
Insight into rechargeable batteries under extreme pressure and gravity for deep space exploration
This work covers recent advancements and outlooks in rechargeable batteries for deep space application, including mass transfer, reaction interface, and core component changes under extreme pressure, microgravity, and supergravity.
J. Mater. Chem. A, 2024,12, 27123-27129
https://doi.org/10.1039/D4TA04410J
Ni-rich layered cathodes in sodium-ion batteries: perspectives or déjà vu?
This Highlight explores advancements in Ni-rich cathode materials for sodium-ion batteries, which offer practical synthesis methods, high specific capacity, and environmental benefits while addressing energy density and cycle life challenges.
J. Mater. Chem. A, 2024,12, 17756-17770
https://doi.org/10.1039/D4TA01989J
Capacity-Weighted Figures-of-Merit for Battery Transport Metrics
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D4TA06041E
Evolution of small molecules as photocatalysts towards production of green hydrogen
Small molecule-based semiconductors for photocatalytic hydrogen gas production are gaining increased interest with the growing need for sustainable and environmentally friendly fuel sources.
J. Mater. Chem. A, 2024,12, 33470-33487
https://doi.org/10.1039/D4TA05353B
Pivotal role of the Pourbaix diagram in electrocatalysis
Pourbaix diagram is a critical tool in electrocatalytic research, driving innovation and improving the reliability of catalyst development.
J. Mater. Chem. A, 2024,12, 27974-27978
https://doi.org/10.1039/D4TA05476H
Revisiting the ionic conductivity of solid oxide electrolytes: a technical review
The present perspective revises the ionic conductivity of highly studied fluorite- and perovskite-based electrolytes for their applications in solid oxide fuel cells (SOFCs) and electrolysis cells (SOECs).
J. Mater. Chem. A, 2024,12, 25696-25714
https://doi.org/10.1039/D4TA03852E
Integrating crystallographic and computational approaches to carbon-capture materials for the mitigation of climate change
This article presents a perspective on the state of the art in the structure determination of microporous carbon-capture materials and paths toward future progress in this field, as discussed the NIST workshop of the same title.
J. Mater. Chem. A, 2024,12, 25678-25695
https://doi.org/10.1039/D4TA04136D
Complementary X-ray and neutron imaging of water electrolysers for green hydrogen production
This perspective discusses the current status and future needs for the use of X-ray and neutron imaging as complementary methods for helping solve key challenges facing electrolyser materials.
J. Mater. Chem. A, 2024,12, 23364-23391
https://doi.org/10.1039/D4TA02885F
Structural determination of covalent organic frameworks through diffraction methods
As an emerging crystalline porous material constructed from organic building blocks linked by covalent bonds, covalent organic frameworks (COFs) have garnered significant interest due to their well-defined pore structures.
J. Mater. Chem. A, 2024,12, 21704-21715
https://doi.org/10.1039/D4TA02312A
Nanoscale spatial and time-resolved mapping in perovskite and organic solar cells: a multimodal technique to visualize the photoinduced charge dynamics
This perspective delves into the nanoscale photodynamics mapping of perovskite (PSCs) and organic solar cells (OSCs) using a multimodal approach to enhance photovoltaic performance.
J. Mater. Chem. A, 2024,12, 16329-16342
https://doi.org/10.1039/D4TA01773K
Recent progress and perspectives of liquid organic hydrogen carrier electrochemistry for energy applications
This perspective delves into electrochemically active and regenerable liquid organic hydrogen carriers (LOHCs), exploring their electrochemical properties and applications in hydrogen storage, regenerative fuel cells, batteries, and flow batteries.
J. Mater. Chem. A, 2024,12, 15580-15591
https://doi.org/10.1039/D4TA01893A
Emerging electrochemical humidity sensors for zero power consumption and self-powered humidity detection: a perspective
This perspective summarizes recent advances in electrochemical humidity sensors and mainly focuses on three aspects: working principles; humidity sensing and power generation performances; self-powered humidity detection system.
J. Mater. Chem. A, 2024,12, 14975-14985
https://doi.org/10.1039/D3TA06283J
Deciphering interfacial charge transfer mechanisms in electrochemical energy systems through impedance spectroscopy
Employing electrochemical impedance spectroscopy as a non-destructive analytical tool for elucidating the interfacial charge transfer in electrochemical energy conversion/storage systems.
J. Mater. Chem. A, 2024,12, 14334-14353
https://doi.org/10.1039/D4TA00537F
Advancing low-dimensional flexible energy devices for wearable technology
This perspective article discusses the research, issues, and prospects of flexible batteries and supercapacitors in terms of one- and two-dimensions, as well as their stretchable, bendable, and twistable properties.
J. Mater. Chem. A, 2024,12, 13672-13681
https://doi.org/10.1039/D4TA02241F
Hydrogen generation from atmospheric water
Green hydrogen, produced by water splitting with renewables, faces water scarcity issues. Atmospheric moisture, a stable source, offers an alternative. This article reviews technologies and challenges of using atmospheric water for H2 production.
J. Mater. Chem. A, 2024,12, 12381-12396
https://doi.org/10.1039/D4TA00848K
Insights into adsorbent materials for lithium extraction by capacitive deionization: reconceptualizing the role of materials informatics
The potential of materials informatics in designing lithium extraction materials for capacitive deionization have been discussed.
J. Mater. Chem. A, 2024,12, 10676-10685
https://doi.org/10.1039/D3TA07069G
A perspective on the building blocks of a solid-state battery: from solid electrolytes to quantum power harvesting and storage
We present a comprehensive perspective on the fundamental components of a solid-state battery, starting from all-solid-state electrolytes and extending to quantum power harvesting and storage.
J. Mater. Chem. A, 2024,12, 690-722
https://doi.org/10.1039/D3TA04228F
Temperature and pressure induced structural transitions of lead iodide perovskites
Conventional lead halide perovskites, APbI3, are excellent materials for photovoltaics and other optoelectronic applications. This perspective highlights the temperature and pressure induced structural phase transitions of CsPbI3, MAPbI3 and FAPbI3.
J. Mater. Chem. A, 2024,12, 19-37
https://doi.org/10.1039/D3TA05315F
Pre-sodiation strategies for constructing high-performance sodium-ion batteries
This review comprehensively summarizes the pre-sodiation strategies for constructing high-performance sodium-ion batteries, highlighting the anode pre-sodiation and cathode pre-sodiation techniques.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06341D
Enabling rational electrolyte design for lithium batteries through precise descriptors: progress and future perspectives
The physicochemical properties accurately captured by the precise descriptors enable researchers to efficiently screen and identify optimal compounds for designing high-performance electrolytes for Li batteries.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA07449A
Fluorinated catalysts for the oxygen evolution reaction: a comprehensive review of synthesis, structure, and performance
Fluorination has been proven to be an effective strategy to boost catalysts' OER performance by significantly reducing overpotential and the Tafel slope while enhancing stability.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06767C
A comprehensive review on the mechanism of contact electrification
This review summarizes the mechanisms, regulations, influencing factors, and application prospects of contact electrification at different interfaces.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA07756C
Advances in the design strategy of bimetallic catalysts for the electrocatalytic reduction of CO2
The bimetallic catalysts are promising for CO2ER. In the current work, bimetallic catalyst preparation methods have been collected and analyzed, challenges and perspectives are also declared.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06805J
Progress in crystalline silicon heterojunction solar cells
Key materials and device structures of crystalline silicon heterojunction solar cells.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06224H
Comprehensive overview of machine learning applications in MOFs: from modeling processes to latest applications and design classifications
This review provides an overview of machine learning (ML) workflows in MOFs. It discusses three rational design methods, focusing on future challenges and opportunities to enhance understanding and guide ML-based MOF research.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06740A
The synergistic effect of MOF and biomass achieving dual breakthroughs in material structure and performance
In order to cope with the environmental crisis and the depletion of non-renewable resources, the combination of metal–organic framework (MOF) and biomass materials has become an important breakthrough in sustainable materials science.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06000H
Recent Progress in Alkali Metal (Li/Na/K) Hybrid-Ion Batteries: Pioneering the Future of Energy Storage
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D4TA06190J
Advancements in Biomass-Derived Cellulose Composite Electrodes for Supercapacitors: A Review
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D4TA05470A
High-temperature oxidation behavior of transition metal complex concentrated alloys (TM-CCAs): a comprehensive review
Commonly used elements of CCAs and the interplay of thermodynamics and kinetics under high temperatures.
J. Mater. Chem. A, 2024,12, 33488-33517
https://doi.org/10.1039/D4TA06071G
Solvation and interfacial chemistry in ionic liquid based electrolytes toward rechargeable lithium-metal batteries
Ionic liquids have further propelled the development of LMBs with their unique properties. In this review, the recent advances by regulating solvation and interfacial chemistry in IL-based electrolytes were systematically discussed.
J. Mater. Chem. A, 2024,12, 33362-33391
https://doi.org/10.1039/D4TA05906A
A review of detecting Li plating on graphite anodes based on electrochemical methods
This review systematically introduces the electrochemical methods for detecting lithium plating and provides an in-depth discussion on the relevant testing principles, advantages, and disadvantages.
J. Mater. Chem. A, 2024,12, 33427-33447
https://doi.org/10.1039/D4TA05871B
Solar stills: the future enabled by machine learning
In this review, machine learning techniques are particularly emphasized along with exploring the differences between solar stills and other solar desalination technologies.
J. Mater. Chem. A, 2024,12, 33448-33469
https://doi.org/10.1039/D4TA06316C
Green ammonia: revolutionizing sustainable energy for a carbon-free future
This review provides a comprehensive analysis of recent advances in green ammonia synthesis and its energy applications, with emphasis on innovations in production technology, storage and transport solutions, and their environmental impacts.
J. Mater. Chem. A, 2024,12, 33334-33361
https://doi.org/10.1039/D4TA07339H
Borocarbonitride materials as metal-free catalysts for advanced catalysis
Borocarbonitride (BCN) materials, as emerging metal-free catalysts, have garnered considerable interest owing to their abundance; their impressive pH tolerance; and the tunable capability of their B, N-doped carbon network and band structures.
J. Mater. Chem. A, 2024,12, 33392-33426
https://doi.org/10.1039/D4TA04797D
Research progress on Cu-ZrO2 catalysts: a systematic review of their preparations, doping, and applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D4TA05742B
Advances in direct optical lithography of nanomaterials
This review presents recent advancements in direct optical lithography of nanomaterials, covering the technique's evolution, key patterning strategies, applications, and future research directions.
J. Mater. Chem. A, 2024,12, 32505-32525
https://doi.org/10.1039/D4TA06618A
Ultraviolet-blocking polymers and composites: recent advances and future perspectives
This review summarizes recent innovations in strategies and mechanisms for fabricating UV-blocking polymers and composites.
J. Mater. Chem. A, 2024,12, 32638-32664
https://doi.org/10.1039/D4TA06335J
Research progress in photocatalytic reduction of CO2 based on metal nanocluster materials
Converting CO2 into hydrocarbons could mitigate the greenhouse effect and address energy crises. Metal nanocluster materials are well-suited for photocatalytic CO2 reduction.
J. Mater. Chem. A, 2024,12, 32665-32688
https://doi.org/10.1039/D4TA06207H
Review of electro-spun carbon nanofiber electrode materials for electrochemical capacitors
Schematic illustration demonstrating various approaches to enhance the electrochemical performance of carbon nanofiber electrode materials.
J. Mater. Chem. A, 2024,12, 32566-32592
https://doi.org/10.1039/D4TA06221C
Sustainable regeneration of a spent layered lithium nickel cobalt manganese oxide cathode from a scrapped lithium-ion battery
Direct regeneration, representing the most advanced technique, is capable of healing spent cathodes under nondestructive condition. This review aims at pushing forward the technical progress of direct regeneration for spent LiNixCoyMnzO2 cathodes.
J. Mater. Chem. A, 2024,12, 32613-32637
https://doi.org/10.1039/D4TA05089D
Electrode–electrolyte interphases in lithium-based rechargeable batteries with ionic liquid electrolytes: recent advances and future perspectives
The characteristics of interphase formation between ionic liquid-based electrolytes and various electrodes are reviewed to support the development of improved electrolyte designs for lithium-based batteries.
J. Mater. Chem. A, 2024,12, 32593-32612
https://doi.org/10.1039/D4TA06184E
The ion effect on electrocatalytic oxidation reactions
The ion effect on anodic reactions manifests three major forms: (1) regulate the adsorption energy through non-covalent interactions, (2) regulate the mass transfer behavior, and (3) regulate the interfacial pH by controlling proton transfer.
J. Mater. Chem. A, 2024,12, 32548-32565
https://doi.org/10.1039/D4TA04113E
Micro/nano encapsulated phase change material: materials, preparation, and emerging advances in the solar energy field
Phase change materials (PCMs) possess high latent heat during the solid–liquid phase transition, making them promising materials for thermal energy storage.
J. Mater. Chem. A, 2024,12, 32526-32547
https://doi.org/10.1039/D4TA03581J
Recent advances in the synergistic effects of organic conjugated materials and quantum dots on solar cells
Quantum dot solar cells (QDSCs) have excellent optoelectronic properties but face challenges in performance and stability. This review highlights advances in organic conjugated materials to improve QDSC performance and outlines key design principles.
J. Mater. Chem. A, 2024,12, 31740-31768
https://doi.org/10.1039/D4TA04233F
Progress in carbon-free oxygen evolution electrocatalysts for high-current-density water electrolysis in acidic media
A review of carbon-free electrocatalysts (CFECs) for high-current-density (HCD) acidic oxygen evolution reaction is presented, including the introduction of proton exchange membrane water electrolysis, along with recent advances and prospects in CFECs.
J. Mater. Chem. A, 2024,12, 31717-31739
https://doi.org/10.1039/D4TA05278A
Cu2O-based catalysts applied for electrocatalytic CO2 reduction: a review
The application of sustainable energy-driven electrocatalytic carbon dioxide reduction reaction (CO2RR) technology enables the synthesis of valuable chemicals and feedstocks.
J. Mater. Chem. A, 2024,12, 31769-31796
https://doi.org/10.1039/D4TA06287F
A holistic review on the direct recycling of lithium-ion batteries from electrolytes to electrodes
First critical review paper on LIBs direct recycling strategies, covering a broader scope with the positive electrode, negative electrode, and electrolyte, while discussing the substantial challenges to their effective implementation.
J. Mater. Chem. A, 2024,12, 31685-31716
https://doi.org/10.1039/D4TA04976D
Recent progress in layered oxide cathodes for sodium-ion batteries: stability, phase transition and solutions
Due to their cost efficiency and the sustainable availability of sodium resources, sodium-ion batteries (SIBs) are regarded as an economical alternative or additional choice to the well-established lithium-ion batteries (LIBs), particularly within extensive energy storing configurations.
J. Mater. Chem. A, 2024,12, 31797-31817
https://doi.org/10.1039/D4TA03372H
Emerging van der Waals material CuInP2S6: physical properties, theories and applications
The review explores CuInP2S6, a promising 2D van der Waals material with remarkable ferroelectric properties and potential applications in neuromorphic computing and memory devices, summarizing its properties, device designs, and future challenges.
J. Mater. Chem. A, 2024,12, 31028-31058
https://doi.org/10.1039/D4TA05024J
Application and prospects of metal–organic frameworks in photocatalytic self-cleaning membranes for wastewater treatment
By loading photocatalytic MOF onto the separation membrane, the self-cleaning function of the membrane can be realized. This paper discusses the structure, synthesis, and properties of photocatalytic MOFs.
J. Mater. Chem. A, 2024,12, 31059-31073
https://doi.org/10.1039/D4TA06433J
Advances in sodium-ion battery cathode materials: exploring chemistry, reaction mechanisms, and prospects for next-generation energy storage systems
Promising cathode materials and advanced operando and in situ measurements to unveil their electrochemical behavior for sodium-ion batteries are comprehensively summarized.
J. Mater. Chem. A, 2024,12, 30971-31003
https://doi.org/10.1039/D4TA03748K
AI and ML for selecting viable electrocatalysts: progress and perspectives
The rising CO2 levels stress the shift to sustainable sources, with electrolysis as a key technology for CO2 removal and clean fuel. AI and ML advancements optimize electrocatalysts, enhancing water splitting and CO2 reduction efficiency.
J. Mater. Chem. A, 2024,12, 31074-31102
https://doi.org/10.1039/D4TA04991H
Microwave absorbing properties of polypyrrole-based 2D nanocomposites
The rise in EM wave pollution creates a demand for effective absorptive materials. PPy is a promising conductive polymer, and PPy-based 2D nanocomposites show potential as effective EM wave absorbers.
J. Mater. Chem. A, 2024,12, 31004-31027
https://doi.org/10.1039/D4TA05676K
MXene-based materials: potential high-performance electrodes for aqueous ion batteries
This review provides a comprehensive analysis of recent advancements in MXene-based AIBs, with a particular emphasis on zinc-ion batteries.
J. Mater. Chem. A, 2024,12, 30944-30970
https://doi.org/10.1039/D4TA05711B
Development and application of Few-shot learning methods in materials science under data scarcity
Machine learning, as a significant branch of artificial intelligence, shortens the cycle of material discovery and synthesis by exploring the characteristics of data.
J. Mater. Chem. A, 2024,12, 30249-30268
https://doi.org/10.1039/D4TA06452F
A review on instability factors of mono- and divalent metal ion batteries: from fundamentals to approaches
Degradation phenomena in different components (cathode, anode, current collectors (CCs)) of mono- and divalent metal-based batteries affect their performance.
J. Mater. Chem. A, 2024,12, 30190-30248
https://doi.org/10.1039/D4TA05386A
Ultrathin two-dimensional membranes by assembling graphene and MXene nanosheets for high-performance precise separation
Ultrathin 2D membranes were assembled by graphene and MXene nanosheets for separation to overcome the “trade-off” limitation between permeability and selectivity.
J. Mater. Chem. A, 2024,12, 30121-30168
https://doi.org/10.1039/D4TA05097E
Electrode process regulation for high-efficiency zinc metal anodes
Regulation strategies for zinc anode ion deposition.
J. Mater. Chem. A, 2024,12, 30169-30189
https://doi.org/10.1039/D4TA05143B
Pore engineering of porous framework materials for efficient SF6 capture
Sulfur hexafluoride (SF6) is an artificial inert gas widely used in the power and semiconductor industries and is known to be a significant contributor to the greenhouse effect due to its high global warming potential.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06241H
Advances in the application of first principles calculations to phosphate-based NASICON battery materials
NASICON potential unlocked: first-principles calculations guide doping for sodium ion battery advancement.
J. Mater. Chem. A, 2024,12, 29335-29354
https://doi.org/10.1039/D4TA04943H
Recent review on self-supported one-dimensional core/shell nanostructures based on WO3 for enhanced electrochromism
This review analyzes the advantages of self-supported one-dimensional core/shell nanostructures (SS1DCSNs) for electrochromic applications and provides an in-depth examination of current literature on WO3-based SS1DCSNs.
J. Mater. Chem. A, 2024,12, 29383-29401
https://doi.org/10.1039/D4TA05474A
From medium- to high-entropy hydroxides for hybrid supercapacitors: a review
This review highlights the recent progress of medium-entropy and high-entropy hydroxides for hybrid supercapacitors. Key synthesis methods and strategies are discussed. Challenges and prospects for these materials are also addressed.
J. Mater. Chem. A, 2024,12, 29402-29431
https://doi.org/10.1039/D4TA05625F
Regulation of electrocatalytic properties of high entropy alloy electrocatalysts for the oxygen evolution reaction
We briefly introduce the four core effects of HEAs and various regulatory strategies for HEA catalysts. This will help scholars further understand the advantages and flexibility of HEAs as catalysts.
J. Mater. Chem. A, 2024,12, 29311-29334
https://doi.org/10.1039/D4TA04984E
Constructing a high-performance bifunctional MnO2-based electrocatalyst towards applications in rechargeable zinc–air batteries
MnO2-based materials are excellent electrocatalysts for rechargeable zinc–air batteries due to their various advantages. The review comprehensively discusses four different strategies to enhance the electrocatalytic performance of MnO2.
J. Mater. Chem. A, 2024,12, 29355-29382
https://doi.org/10.1039/D4TA05182C
Exploring the potential of gas atomized high entropy alloys in thermal spray coatings – a comprehensive review
The microstructural, mechanical, wear & corrosion behaviours of gas-atomized HEA coatings obtained by various thermal spray techniques are explored. Diverse applications and current trends of HEA coatings are discussed.
J. Mater. Chem. A, 2024,12, 29432-29468
https://doi.org/10.1039/D4TA04512B
Advances in radiative cooling materials for building energy efficiency: a decade of progress
In this critical review, we present a comprehensive analysis of the advancements in RSC technology over the past decade, a fast-developing period, to further facilitate its practical applications in buildings.
J. Mater. Chem. A, 2024,12, 28682-28710
https://doi.org/10.1039/D4TA04942J
Boosting the efficiency of electrocatalytic water splitting via in situ grown transition metal sulfides: a review
This review provides an in-depth analysis of the key aspects related to in situ grown TMS electrodes, including the selection of TMS active materials, various substrates, and materials engineering.
J. Mater. Chem. A, 2024,12, 28595-28617
https://doi.org/10.1039/D4TA06197G
Basics, developments, and strategies of transition metal phosphides toward electrocatalytic water splitting: beyond noble metal catalysts
This review covers the comprehensive information of basic water splitting electrolysis, catalyst manufacturing, performance enhancement strategies, and perspectives of transition metal phosphide electrocatalysts considering the recent studies.
J. Mater. Chem. A, 2024,12, 28574-28594
https://doi.org/10.1039/D4TA04455J
Electrolyte regulation methods for improving the cycle life of zinc metal anodes
Three electrolyte regulation methods, including electrolyte solvation structure regulation, EDL regulation, and SEI regulation, are discussed in detail. Each method targets a distinct aspect: bulk electrolyte, EDL electrolyte, and SEI, respectively.
J. Mater. Chem. A, 2024,12, 28658-28681
https://doi.org/10.1039/D4TA05590J
Artificial CO2 photoreduction: a review of photocatalyst design and product selectivity regulation
We summarized the design strategies for photocatalysts to enhance CO2 reduction and accepted pathways for selective photocatalytic CO2 conversion.
J. Mater. Chem. A, 2024,12, 28618-28657
https://doi.org/10.1039/D4TA04600E
About this collection
This collection contains recent Review-type articles published by Journal of Materials Chemistry A, the home for high impact applications, properties and synthesis of exciting new materials for energy and sustainability. New articles will be added to this collection as soon as possible after publication.