Issue 59, 2016
From the journal:

Chemical Communications

Ni-based heterogeneous catalyst from a designed molecular precursor for the efficient electrochemical water oxidation†

Denis A. Kuznetsov,*a   Dmitry V. Konev,a   Natal'ya S. Komarova,a   Andrey M. Ionov,b   Rais N. Mozhchilb  and  Ivan V. Fedyaninc  

* Corresponding authors

a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, Russian Federation
E-mail: kuz_da@icp.ac.ru

b Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, Russian Federation

c A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation

Abstract

Bimetallic Ni–Mo alkoxide was synthesized and exploited as the single-source precursor for the solution-processed deposition of the mixed-oxide layers on different conducting surfaces. Upon potential cycling in 1 M NaOH, these composites convert, in situ, into highly porous NiOx/NiOOH catalysts characterized by the high electrocatalytic activity for water oxidation under both basic (pH 13.6) and near neutral (pH 9.2) conditions.

Graphical abstract: Ni-based heterogeneous catalyst from a designed molecular precursor for the efficient electrochemical water oxidation

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Article information

DOI
https://doi.org/10.1039/C6CC04400J
Article type
Communication
Submitted
25 May 2016
Accepted
17 Jun 2016
First published
17 Jun 2016

Chem. Commun., 2016,52, 9255-9258

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Ni-based heterogeneous catalyst from a designed molecular precursor for the efficient electrochemical water oxidation

D. A. Kuznetsov, D. V. Konev, N. S. Komarova, A. M. Ionov, R. N. Mozhchil and I. V. Fedyanin, Chem. Commun., 2016, 52, 9255 DOI: 10.1039/C6CC04400J

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