Graphene is prized for its large surface area and superior electrical properties. Efforts to maximize the electrical conductivity of graphene commonly result in the recovery of sp²-hybridized carbon in the form of reduced graphene oxide (rGO). However, rGO shows poor dispersibility and aggregation when mixed with other materials without hydrophilic functional groups, This could lead to electrode delamination, agglomeration, and reduced efficiency. This study focuses on the impact of solvothermal reduction on the dispersibility and capacitance of rGO compared with chemical reduction. The results show that the dispersibility of rGO-D obtained through solvothermal reduction using N,N-dimethylformamide improved compared to that obtained through chemical reduction (rGO-H). Furthermore, when utilized as a material for CDI, an improvement in deionization efficiency was observed in the AC@rGO-D-based CDI system compared to AC@rGO-H and AC. However, the specific surface area, a key factor affecting CDI efficiency, was higher in rGO-H (249.572 m² g⁻¹) than in rGO-D (150.661 m² g⁻¹). While AC@rGO-H is expected to exhibit higher deionization efficiency due to its greater specific surface area, the opposite was observed. This highlights the effect of the improved dispersibility of rGO-D and underscores its potential as a valuable material for CDI applications.