Irradiation of arylazirenes gives 1,3-diazabicyclo[3,1,0]hex-3-enes via 1,3-dipolar addition of an initially generated nitrile ylide on to a ground state arylazirene molecule.
A. Padwa, J. Smolanoff and S. I. Wetmore, J. Chem. Soc., Chem. Commun., 1972, 409 DOI: 10.1039/C39720000409
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