An analysis of the circular and linear dichroic spectra of exocyclic olefins substantiates the view that the octant rule cannot be applied to the higher wave-length Cotton effects of olefins.
A. Yogev, J. Sagiv and Y. Mazur, J. Chem. Soc., Chem. Commun., 1972, 411 DOI: 10.1039/C39720000411
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