A resonance-Raman spectrum of the complex K4Mo2Cl8 has been recorded with 488·0 and 514·5 nm excitation; five harmonics of ν1(the “Mo–Mo stretching” fundamental) have been located accurately, and from these data it is deduced that ω1= 347·1 ± 0·5 cm–1 and X11= 0·50 ± 0·08 cm–1.
R. J. H. Clark and M. L. Franks, J. Chem. Soc., Chem. Commun., 1974, 316 DOI: 10.1039/C39740000316
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