Addition of 2 equiv of potassium tri-s-butylborohydride to copper(I) iodide produces both sp3 and sp2 hybridized organic halides in addition to various other organic functional groups.
T. Yoshida and E. Negishi, J. Chem. Soc., Chem. Commun., 1974, 762 DOI: 10.1039/C39740000762
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