Issue 11, 1975

Reaction of tellurium hexafluoride with ethylene glycol and other polyhydric alcohols

Abstract

Tellurium hexafluoride reacts with ethylene glycol under a range of experimental conditions to yield the compounds F5TeO·[CH2]2·OTeF5, cis-(·O·[CH2]2·O·)TeF4, cis- and trans-(·O·[CH2]2·O·)2TeF2, and (·O·[CH2]2·O·)3Te. Reactions with other polyhydric alcohols, e.g., HO·[CH2]3·OH, HO·CH2·CH(Me)·OH, HO·[CH2]4·OH, HO·[CH2]10·OH, HO·CH2·CH(OH)·CH2·OH, MeC(CH2OH)3, and C(CH2OH)4 have also been investigated and the properties of the products are discussed.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 1033-1036

Reaction of tellurium hexafluoride with ethylene glycol and other polyhydric alcohols

G. W. Fraser and G. D. Meikle, J. Chem. Soc., Dalton Trans., 1975, 1033 DOI: 10.1039/DT9750001033

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