The ketone (1), derivable from methyl-α-D-glucopyranoside in four steps, may be converted into one enantiomer, the other enantiomer, or a mixture of both enantiomers of frontalin in 13% overall yield.
D. R. Hicks and B. Fraser-Reid, J. Chem. Soc., Chem. Commun., 1976, 869 DOI: 10.1039/C39760000869
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